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Lithium nitride : ウィキペディア英語版
Lithium nitride

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Lithium nitride is a compound with the formula Li3N. It is the only stable alkali metal nitride. The solid is a red or purple color and has a high melting point.
==Preparation and handling==
Lithium nitride is prepared by direct combination of elemental lithium with nitrogen gas:〔E. Döneges "Lithium Nitride" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 984.〕
:6 Li + N2 → 2 Li3N
Instead of burning lithium metal in an atmosphere of nitrogen, a solution of lithium in liquid sodium metal can be treated with N2.
Lithium nitride reacts violently with water to produce ammonia:
:Li3N + 3 H2O → 3 LiOH + NH3


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